for learning c#
http://www.deitel.com/books/#net
or
http://www.amazon.com/gp/product/0596006993/ref=pd_bxgy_text_b/102-7924748-7891357?ie=UTF8

for ASP.NET
http://www.amazon.com/gp/product/0596004877/sr=8-4/qid=1155498387/ref=pd_bbs_4/102-7924748-7891357?ie=UTF8

If your just starting programming the beginner series isn't beginner enough... At least not enough for me when I first started trying.

I like the wrox series of books, they are very well laid out. Below is a link to the starter C# book that I own and recommend above all others.

Hope this helps!
Jason

p.s. I'm sure wrox also makes a asp book as well (search on amazon) and the quality of all their books are stellar.